Wimbledon -- Women's third-round matches

Wimbledon order of play star Rafael Nadal

After defending champion Garbine Muguruza suffered a shock exit in the second round on Thursday, it was 10th seed Keys' turn to endure an unexpected 7-5, 5-7, 6-4 third round defeat.

The 20-year-old is ranked 68th and has never been to the third round at a grand slam tournament.

Madison Keys became the seventh woman seeded in the top 10 to crash out of Wimbledon as the American was stunned by Russian qualifier Evgeniya Rodina on Friday.

The match on Monday will also be a tussle between two of the tour's mothers.

Serena Williams, the seven-time Wimbledon victor, is seeded 25th after her tentative return from the birth of her first child. "She played really well".

Her sister Serena Williams is still going strong, though, after overcoming her toughest test so far this week.

Cilic was runner-up to Roger Federer past year and showed great form by beating Novak Djokovic in the Queen's Club final last month. "So it will be great to play against her".

Keys, who was the US Open runner-up previous year, crashed out 7-5 5-7 6-4 to the Russian on a baking hot Court Three.

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Zverev erased a 2-1 deficit in sets three times to reach the quarterfinals of the French Open, his best result at a Grand Slam.

Keys lost in three sets behind a faltering serve, and gave up seven break points to Rodina.

Nadal won only 64 per cent of points on his first serve and faced 13 break points - including three in the first game of the match - but he saved 11 of them and converted five of his own to wrap up the win in under 2 1/2 hours on Centre Court. After the double fault in the first set, Mladenovic appeared to lose her confidence.

"I tried to hit the ball hard and fight for every ball and I think in the end that's why I won".

Makarova, who made the quarter-finals four years ago, beat a weary-looking Lucie Safarova of the Czech Republic 4-6, 6-1, 6-4.

She rallied to level the third-round match before Rodina sealed a maiden place in the last 16 of a major.

Nick Kyrgios, the 15th seed, also advanced in straight sets, beating Dutchman Robin Haase 6-3 6-4 7-5 to book a date with Kei Nishikori, who ousted Kyrgios's fellow Australian Bernard Tomic 2-6 6-3 7-6 (9-7) 7-5.

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